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Gems
are often enhanced to improve their appearance, color, wearability
or lapidary qualities. These treatments can include transforming
one stone into another entirely though artificial means. Obviously
this will have a major effect on the healing and magical properties
of the resulting stone. Other treatments may involve irradiating
or heating the stone or impregnating it with a chemical or colorant.
These treatments diminish the value of the stone for magical and
healing purposes. Some stones often found commercially as jewelry
are not naturally occuring and only exist as man made or altered
materials. Among these are Aqua Aura Quartz, Siberian Blue Quartz,
Oro Verde Quartz, Electric Blue Topaz, Gold stone, Hematine, dyed
Howellite as well as others. Some people ascribe healing properties
to these stones and feel that they are useful and they may be, but
they have been altered and I personally feel that this dimishes
their value.
Heating
Many
gems are routinely heated under controlled conditions to improve
color (aquamarine, sapphire, ruby, tourmaline), alter color (sapphire,
amethyst to citrine, topaz, zircon), or improve clarity (sapphire,
ruby). Since natural heating also occurs (e.g., in volcanic areas),
the artificial effects are sometimes indistinguishable from natural
effects. In most cases, the results of heat treatment are permanent.
Temperatures used for heat treatments vary, depending on the material
and desired color. Sometimes low temperature, such as that from
an alcohol lamp, will change brown topaz to pink; very high temperatures,
as high as 2050 degrees C, are needed for other alterations, such
as titanium-rich milky sapphires to blue.
Colorless Coatings
The
purpose of coatings is to protect dye treatments, to improve the
polish by masking small scratches, grainy textures, or surface irregularities,
and to stabilize porous gemstones (Hurlbut and Kammerling, 1991,
p. 174-5). These treatments are used on gem material composed of
more than one mineral, such as jadeite, nephrite, or lapis lazuli,
to aid in polishing. Aggregate gem surfaces may be uneven and vary
in hardness. Gems coated because of low hardness include alabaster,
marble, rhodochrosite, soapstone, turquoise, serpentine, and amazonite
feldspar. Besides low hardness, some gems are porous and the coatings
keep the surface from accumulating skin oils and dirt. Colorless
coatings include waxes, paraffin, and plastics. To detect coatings,
a hot needle may cause wax and paraffin to liquefy and flow, whereas
plastics will have an acrid odor.
Irradiation
Artificial
irradiation is the most controversial process used to alter a gems
appearance and many times the colors are not stable in light or
low heat. Health risk is a concern, as there are still questions
about the acceptable levels of radioactivity a gem can carry. The
Nuclear Regulatory Agency is currently working on establishing standards.
"Commercially three types of facilities are used to treat gemstones:
gamma ray facilities (often using cobalt-60), linear accelerators
(producing high-energy electrons), and nuclear reactors (producing
high-energy neutrons) (Hurlbut and Kammerling, 1991, p. 170). The
GIA Gem Trade Laboratory can test gems and grade for acceptable
or unacceptable radiation levels (Matlins and Bonanno, 1998, p.
126). Radiation
is energy emitted in the form of particles or electromagnetic rays.
Ionizing radiation creates crystal structure defects, which can
take colorless beryl and turn it to golden beryl or heliodor and
intensify the pink or red in tourmaline. Intense yellow or orange
colored sapphire is irradiation induced, but the color is not stable.
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Quartz species
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Oro
Verde, lemon citrine, smoketrine and most dark gray smoky quartz
without any brown tones are all irradiated. Citrines are often heat
treated to improve color and give a reddish tint. Most citrine is
amethyst that has been heat treated. Some smoky can be heated to
create citrine. Prasiolite is heat treated amethyst and citrine
from one locality.
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Yellow
Quartz- Known commercially as "Oro Verde Quartz",
this is irradiated clear quartz and is available in colors
ranging from gold to yellow/green. See illustration on right.
The resulting color is not always stable and may be reversed
by heating the stones to high temperatures
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Smoky
Quartz- Can be created from irradiated clear quartz and may also
be heat treated to lighten very dark colored material. In the first
case the stone has been created from another material and the result,
whatever the color, is still clear quartz magically and for healing
purposes, not smoky quartz. The effects of irradiation can be unstable
and in many cases are reversible by heating the stone to high temperatures.
The lightening of the color does not significantly affect the properties
of the stone. Irradiation is used on clear quartz to produce a smoky
brown to black color.
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Rose
Quartz- Generally not treated, but gem material may be heated to
make it more transparent. Very clear material is somewhat unusual
and should be priced higher. Most rose quartz is "silky"
meaning that it has a satiny, translucence to it rather than a clear
look like many other quartzes. It is often completely opaque except
at the edges. It should be pale to bright pink, or sometimes peachy
pink.
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Citrine
Quartz- Much of this in the brighter, yellow-gold colors such
as that on the right is heated amethyst, not citrine. It naturally
ranges in color from orange to orange/red, yellow, gold, brown/orange.
The treated material is not citrine magically or for healing
purposes, it is still amethyst.
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Aqua
aura quartz- This is not a natural quartz, it is a clear quartz
crystal coated with gold which is then subject to electrical
current in a vacuum chamber. As the crystal is heated to a
high temperature, the gold bonds to the surface of the quartz
to create a transparent aquamarine color. The coating is permanent.
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Siberian
Blue Quartz- This is a laboratory grown crystal produced in
Russia. It is created by combining cobalt with clear quartz
and regrowing a crystal using a hydrothermal process. |
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Black
onyx- This stone is almost always agate that has been impregnated
with sugar, which is then carbonized by acid to turn the stone
black. This treatment results in a stone that is uniformly
black with no evident layering of the color. Onyx naturally
tends to have banded layers of color. Agate and onyx are both
microcrystaline quartz. The treatment is stable and durable,
it is not affected by water or wear. The method is to soak
the stone in a sugar solution, then in concentrated sulfuric
acid. This treatment produces a dyed black chalcedony, sold
as black onyx. This treatment cannot presently be detected
but because natural gem-quality black chalcedony is extremely
rare, this dye treatment is the norm (Hurlbut and Kammerling,
1991, p. 177).
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| Carnelian-
Can be created by heating of yellow to light brown chalcedony
(which contains iron) to produce red carnelian (converting limonite
to hematite). |
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Prasiolite-
Heating purple quartz in the presence of iron creates green
quartz, marketed as prasiolite. Prasiolite, also spelled praziolite
also called vermarine. It is a relatively rare gemstone which
comes into being when certain amethysts from the Montezuma deposit
in Brazil are exposed to heat of 932 degrees F. This elicits
their green color, as well as the nickname 'green amethyst'.
Prasiolite (Greek-leek-green stones) is not found in nature.
In sunlight, the color commonly fades. |
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Red
Tigers Eye- Heating golden tiger eye can produce a red variety
(dehydrating the limonite to produce hematite). |
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| Other Mineral Species |
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Emerald-
You can assume every cut emerald on the market is treated
unless it is specifically stated otherwise. Nearly every emerald
is oiled to improve it's appearance and hide flaws. Emeralds
are naturally subject to inclusions which may be severe, impregnating
them with oil tends to minimise the inclusions and improve
the color saturation. Emerald has the longest history of fracture
filling, due to its popularity and its tendency to be highly
included and fractured. Natural oils have traditionally been
used for fillings, such as Canada balsam, cedarwood oil, mineral
oil, cooking oil, and even motor oil! Cleaning the stone and
heat can remove these oils. Recently synthetic resins have
been used, such as Opticon, which is more permanent than the
natural oils. Treated surfaces are best detected with magnification,
in reflected light; dark-field illumination is best for internal
break fillings. A flash effect, blue (indicates epoxy resin),
orange-yellow (probably epoxy resin), or yellow (sometimes
the residue left after the filling has come out), can confirm
the presence of resin. Flattened gas bubbles can be trapped
in the filling material, slight colored outline of the fracture,
and/or areas of low relief can be clues to fracture filling.
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Topaz-
The blue is almost always irradiated and heated. Naturally
smoky in color, the material is treated and the color changes
to various shades of bright blue. The original stone was topaz,
and the resulting stone is still topaz, only the color is
changed. Brown to orange topaz is colored in part because
of chromium, and also because of crystal structure damage.
Heating this topaz repairs the structural damage, reducing
the yellow component, and turning the brown to orange topaz
pink. The material has stronger dichroism than untreated pink
topaz. Topaz that is irradiated produces a crystal structural
damage, creating a yellow and blue color; heating follows
irradiation, reducing the yellow component, and leaving blue
as a final color. Blue topaz is the most commercially produced
irradiated gemstone in today's market. Natural blue topaz
is pale but radiated material creates a deep blue, referred
to as Electra Blue, Swiss Blue, and Max Blue,
among other names. Irradiating topaz may produce a secondary
yellow to brown color that is converted to blue with heat
treatments. "Linear accelerator (linac) treatment is a preferred
enhancement method for topaz today (Hurlbut and Kammerling,
1991, p. 171). Darker blues are attained, called sky blues,
and the process must be followed by heating. The "London Blue"
coloration is created using irradiation from nuclear research
reactors, which produces residual radioactivity causing the
material to be stored until the induced radioactivity decays
to acceptable levels.
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Turquoise-
Natural turquoise of lower quality is often very crumbly and
porous so it is often sealed with wax or plastic resin to
stabilize it, minimise staining, to protect it from acidic
skin oils and improve the color. Sometimes turquoise is completely
created from ground up turquoise scrap that is impregnated
with plastic and heated under pressure to rebond it into a
solid mass of material which is then cut as if it were a natural
material. These treatments are not disclosed to the buyer
generally.
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Hematite-
Much of the hematite used in jewelery, particularly beads, is actually
hematine, which is both a synthetic and imitation. Hematine is a
created simulator of stainless steel with chromium and nickel sulfides.
It is made to imitate hematite. The two can be distinguished by
a streak and magnetism. Hematite has a reddish-brown streak, whereas
hematine has a brown-black streak (this test is destructive though!).
Hematine is strongly magnetic, whereas hematite is typically not
magnetic.
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Aquamarine-
Aquamarine is often heat treated to reduce the green/blue
color and improve the blue color. It is safe to assume most
have been heated. Heating turns the originally blue-green
stones to light blue. The natural color is on the right in
the photo, the heated result on the left. This change in color
doesn't affect the stone magically or for healing purposes.
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Hiddenite-
The more common variety of spodumene, Kunzite, pink spodumene,
can be irradiated to produce the green variety, known as hiddenite,
but it is not a stable color.
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Heliodor-
Ionizing radiation creates crystal structure defects, which
can take common, inexpensive, colorless beryl and turn it
to golden beryl or heliodor.
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Zircon-
Reddish-brown zircons can be heated to 900-1000 degrees C,
in a reducing atmosphere, to produce blue, colorless, or some
undesirable color. The undesirables are then heated in an
oxidizing environment, converting them to colorless or yellow,
red, or orange colors.
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